Photothermische Energiespeicherrohstoffe
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Solar-driven chemistry is an attractive way to solve energy and environmental problems, among which photothermal chemistry (PTC) can realize full-spectral utilization of solar radiation and driving c
What is photothermal chemistry (PTC)?
This hybrid strategy is commonly known as “photothermal chemistry” or “photo-thermochemistry” (PTC), where thermal and non-thermal effects may work together in chemical reactions. The number of studies on PTC has been increasing year by year, especially in the last decade, as shown in Figure 2.
What is PTC-T (thermal-dominant photothermal chemistry)?
For convenience, we term this as PTC-T (thermal-dominant photothermal chemistry). PTC-T follows the L–H–C strategy, where the chemical reactions are driven by heat that is converted from solar energy and the reaction mechanism can be expounded by thermochemistry.
What are the different types of photoelectrochemistry systems?
There are several types of systems that follow this strategy: photovoltaic electrochemistry (PV-EC), photoelectrochemistry (PEC), and photovoltage-assisted photoelectrochemistry (PV-PEC). PV-EC first generates electrical energy from sunlight, and then drives chemical reactions by means of electrochemistry.
How does a photochemical device work?
In the photochemical device, the ultraviolet–visible light photons are absorbed to drive the isomerization of norbornadiene derivatives; while the rest of photons corresponding to the visible-infrared spectrum are transmitted to thermochemical reactors, providing heat for methanol decomposition.